Vapo-rub was a vaseline based ointment. It came in a wide mouth jar. I think that little bottle held some kind of drops, but I can't remember what kind. Cute , but fairly common, so not much value.
Yeah it's Vicks-branded something, but not the Vapo-Rub. Not sure what exactly these contained but they're very common unfortunately. Dates from probably the 30s-50s and not really worth anything more than a dollar sadly.